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Production of ultra-pure hydrogen from wood

 

This project focuses on an innovative process for the production of ultra-pure hydrogen from wood. The process is based on the redox reactions of iron oxide and could contribute towards reducing the transport and electricity sector's dependence on fossil sources of energy.

Project description (completed research project)

To produce hydrogen on the basis of wood in small, decentralised facilities, the researchers modified the conventional iron-steam-process and added a gasification process. To avoid a reduction in the reactivity of the iron oxide based oxygen carriers after a few cycles, iron oxide has to be stabilised, e.g. through the addition of high Tammann temperature metal oxides such as alumina. One challenge to overcome was that the synthesis gas produced contained impurities, such as tars and sulphur containing compounds. The project team developed novel oxygen carrier formulations that showed a high tolerance to impurities of the synthesis gas and that minimized the extent of carbon deposition.

Background

Hydrogen, when produced sustainably, could contribute to a reduction in anthropogenic CO2 emissions and reduce the dependence of Switzerland on importing energy. Hence the efficient production of hydrogen from renewable resources such as wood is an active area of research. Furthermore, hydrogen can only be used in low-temperature fuel cells if it is highly pure. The prevailing method of hydrogen production involves the steam reforming of methane, a process that produces also carbon dioxide. Hydrogen produced through a reforming process needsto be subjected to costly gas purification operations in order to reduce the content of carbon monoxide to the relevant standard levels.

Aim

The main goal of this research project is to develop innovative, iron-based redox materials with the following properties:

  • high content of active material;
  • fast kinetics;
  • mechanical stability;
  • the capability to crack tars (i.e. to split them into hydrocarbons with shorter chains);
  • resistance to hydrogen sulphide and components of wood ash;

The researchers produced such materials using a sol-gel method, which allows for the synthesis of nano-structured redox materials. The materials were tested a fixed-bed reactor. Another important facet of this project aimed a coupling directly the fixed-bed reactor to a wood gasifier. Such a process operation might be interesting for industrial application.

Relevance

The results of this project can contribute to a more sustainable and efficient production of hydrogen and help in reducing Switzerland's dependency on fossil fuel.

Results

The project included two separate studies that utilize either conventional oxygen carriers or novel oxygen carriers that are enriched with copper oxide. Both studies showed that hydrogen impurities such as carbon monoxide could be minimized through advances in the formulations of the oxygen carriers, e.g. though the addition of copper oxide. Another important factor is the selection of appropriate contacting and reaction times.

Original title

Distributed production of ultrapure hydrogen from woody biomass

Project leader

  • Prof. Christoph Müller, Laboratory of Energy Science and Engineering, Eidgenössische Technische Hochschule Zürich

 

 

Further information on this content

 Contact

Christoph Müller Laboratory of Energy Science and Engineering D-MAVT
ETH Zürich
Leonhardstrasse 27
LEO D7
8092 Zürich +41 44 632 34 40 muelchri@ethz.ch